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|Section2= |Section8= }} Chloryl fluoride is the chemical compound with the formula ClO2F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen sources.〔Chrisie, K. O.; Wilson, R. D.; Schack, C. J. "Chloryl fluoride" ''Inorganic Syntheses'', 1986, volume 24, pages 3–5. ISBN 0-471-83441-6〕 It is the acyl fluoride of chloric acid. ==Preparation== ClO2F was first reported by Schmitz and Schumacheb in 1942, who prepared it by the fluorination of ClO2.〔Schmitz, H.; Schumacheb, H. J. "Über eine neue Reaktion des Chlordioxyds. Die Bildung einer Verbindung der Formel ClO2F" ''Zeitschrift für anorganische und allgemeine Chemie'' 1942, Volume 249, pp. 238–244. DOI 10.1002/zaac.19422490302〕 The compound is more conveniently prepared by treatment of sodium chlorate and chlorine trifluoride and purified by vacuum fractionation, i.e. selectively condensing this species separately from other products. This species is a gas boiling at −6 °C: :6 NaClO3 + 4 ClF3 → 6 ClO2F + 2 Cl2 + 3 O2 + 6 NaF 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「chloryl fluoride」の詳細全文を読む スポンサード リンク
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